化學(xué)品安全技術(shù)說明書MSDS

第一部份     化學(xué)品及企業(yè)名稱

Section1 Material and company identification

 

化學(xué)中文名稱: KD-92735磨砂漆

Commodity Name: KD-92735 Sanding paint  俗名：磨砂漆  

Common Name: Paint      

企業(yè)名稱：東莞市愛飾麗化工有限公司   

Company Name: Dongguang Ashley Industry Ltd.CO

地址：東莞市樟木頭鎮(zhèn)柏地工業(yè)區(qū)

Address: Baidi Industry Zone, Zhangmutou,Dongguang

Fax : 0769-87198956

企業(yè)應(yīng)急電話： 0769-87198956

Company Emergency Tel: 0769-87198956

安全技術(shù)說明書編號：MSDS-99

MSDS No: MSDS-113

生效日期： 2019年11月10日

Effective Date: Feb 22^th, 2019

國家應(yīng)急電話：0532-83889090

National Emergency Tel: 0532-83889090

 

第二部份    成份/組成信息

Section2 composition/information on ingredients

 

KD-92735 Sanding paint的成份

成份 components	CAS-NO	含量 content	用途 usage
丙烯酸樹脂 Acrylics Acid Resin	79-10-7	47%
啞粉 Dumb powder	1213-86-4	20%
醋酸丁脂 N-butyl Acetate	111-76-2	12.5%
醋酸乙脂 Ethyl Acetate	110-80-5	11.5%

                                                                   

第三部份    危險性概述

 

危險性類別：第三類易燃液體，3.3高閃點易燃液體。

Hazard Class: Class 3.3 high flash point flammable liquid

危險性源述：本品易燃，對環(huán)境有害，對水體可造成污染。

Hazard Assessment: Inflammable, environmentally harmful and pollute the water resource       

侵入途徑：吸入，食入，經(jīng)皮膚吸收。

Invasion Way: Inhale, ingestion and absorb by skin

健康危害：1）、成份中的乙酯屬低毒類，有麻醉作用。其蒸氣刺激眼、皮膚和粘膜，造成眼角膜渾濁。其高濃度蒸氣能引起肝、腎充血。持續(xù)性大量吸入，則可發(fā)生急性肺水腫。嗅覺網(wǎng)濃度270MG/M³，TJ36-79規(guī)定車間空氣中最高容許濃度為300MG/KG。

Health Hazards:

1)Components of Ethyl Ester is an anesthetic low toxicity material, its vapor has irritaiton to eye, skin and mucous, cornea opacification may produce. High concentration of vapor may cause bleeding in the lungs and kidney; Continuous inhale large quantity will lead to acute pulmonary edema; The concentration of olfaction net reaches 270MG/M3,TJ36-79, the max allowable concentration in the workshop is 300MG/KG.

 

2）、成份中的丁酯對中樞神經(jīng)有抑制作用，吸入其蒸氣對眼及上呼吸道有強烈刺激作用，且刺激肺胞粘膜，引起肺充血和支氣管炎?？诜r刺激消化器官，引起胃、十二指腸和腸間膜充血。但乙酸丁酯在一般條件下毒害不大。上述癥狀在不與乙酸丁酯接觸后很快消失，且無后遺癥。

2) Components of N-butyl ester has inhibition to central nervous, intake its vapor, pulmonary congestion occurs when strongly irritates the eye, upper respiratory and stimulate air cell mucosa. Orally intake stimulates digestive organs, congestion occurs among stomach, duodenum and intestinal membrane. While N- butyl acetale has less harmful generally. The symptom mentioned above will disappear quickly and without sequelae if no contact with it.

 

        3）、成份中的丁酮可能抑制中樞神經(jīng)，吸入其蒸氣時刺激眼睛與氣管，引起頭痛、惡心，頭昏眼花、困倦。

Components of Butanone can inhibit central nervous. Irritating eyes and air tube thus may lead to headache, nausea, dizziness and sleepy.

 

4）、成份中的異丙醇微毒類，生理作用與灑精相似，毒性、麻醉性以及對上呼吸道粘膜的刺激都比酒精強，在體內(nèi)幾乎無蓄積，殺菌能力比酒精強2倍。

Components of Isopropanol is a less toxic group. Physiological effect is similar to alcohol while toxicity and narcotic stimulate to upper respiratory more strong than alcohol. Accumulation hardly available in body but double time of sterilization than alcohol.

 

 

 

第四部分 急救措施

Section4 first-aid measures

 

皮膚接觸：立即脫去污染的衣服，再用肥皂水和清水徹底沖洗皮膚。

Skin Exposure: Take off the polluted clothes immediately, then rinse thoroughly the skin with soup and water.

眼睛接觸：立即翻開上下眼瞼，用流動清水或生理鹽水沖洗至少15分鐘，嚴(yán)重者送醫(yī)院進(jìn)行治療。

Eye Exposure: eyelids turned, wash with running water or saline for at least 15 minutes, go to the doctor if seriously.

 

吸    入：大量吸入乙酯、丁酯、丁酮、異丙醇的蒸汽后，應(yīng)迅速脫離現(xiàn)場至空氣完全清新處，保持呼吸道暢通，呼吸困難時給輸氧。如呼吸停止，應(yīng)立即進(jìn)行人工呼吸和心臟按摩、就醫(yī)。

Inhale: Intake the vapor of Ethyl Ester,N- butyl ester, Butanone and Isopropanol in a large quantity should be run away to a fresh air area and keep respiratory comfortable. Taking oxygen if breath hard; mouth-to-mouth and heart massage if respiratory arrest occurs. Otherwise, go to the doctor.

 

食     入：飲足量溫水，催吐，就醫(yī)。

Ingestion: Drink enough warm water, vomiting and go to the doctor.

 

第五部分 消防措施

Section7 fire-fighting measures

 

危險特性：

   成份中的甲苯、乙酯、丁酯、丁酮、異丙醇其蒸氣與空氣形成爆炸性混合物，遇明火，

高熱能引起燃燒，爆炸，與氧化劑能發(fā)生強烈反應(yīng)，其蒸氣比空氣重，能在較低處擴(kuò)散到相

當(dāng)廣泛的地方。遇火源引著回燃，若遇高熱，容器內(nèi)壓力增大，有開裂和爆炸的危險。流速

過快的情況下，容易產(chǎn)生和積蓄靜電。成份中的丙烯酸樹脂是有機(jī)高從子聚合物，在適當(dāng)?shù)?/a>

情況下也能燃燒。

Dangerous Features: The vapors and air of Methyl Benzene, Ethyl Ester,N- butyl ester, Butanone and Isopropanol may form explosive mixture. Fire and explosion cause when meeting open fire and high heat. It reacts strongly with oxidant. Overflow can be easily produce and accumulate the statics. Its vapor is heavier than air so that it can spread from a lower area to a quiet far area. Fire backdraft will happen when meeting the open fire.

有害分解物：不完全燃燒會產(chǎn)生一氧化碳

Hazard products of combustion: co will produce when incompletely burn

 

滅火方法：滅火劑、干粉、二氧化碳、砂土。

Extinguishant: appropriate foam, dry chemical, Coz, sand, and water fire invalid.

 

滅火注意事項：噴水冷卻容器，可能的話將容器從火場移至空曠處。

Extinguishing Notice: Water spry cools the container and move to the open area if possible.

第六部分 泄漏應(yīng)急處理

Section6 Leakage Emergency Treatments

 

 應(yīng)急處理：應(yīng)熄滅一切明火，禁止吸煙。避免火花，從速撤離現(xiàn)場，避免吸入其氣體。盡可能切斷泄露源，防止進(jìn)入下水道。排洪溝與限制性空間。

Emergency Treatments: cut off the power and fire. Evacuate the people from leak contaminated areas to a safe area quickly and isolated, strict restrictions on access. Recommend emergency personnel wearing positive pressure self-contained breathing apparatus and protective clothing. Cut off the leaking resource asap. Prevent the leak into the confined spaces like sewers or flood discharged trench.

 

清除方法：小量泄露，盡可能將泄露液收集在密閉容器內(nèi)，用砂土、活性碳或其它惰性材料吸收殘液。也可以用不燃性分散劑制成的乳液刷洗，洗液稀釋后放入廢水區(qū)。

          大量泄露，構(gòu)筑圍堤或挖坑收容。用泡沫覆蓋，降低蒸氣災(zāi)害。噴霧狀水冷卻和稀釋蒸氣、保護(hù)現(xiàn)場人員。用防爆泵轉(zhuǎn)移至槽車式專用收集容器內(nèi)，回收式運至廢物處理所處理。

Clearing Methods:

Small Leaking: collect the leaking liquid into the sealing containers asap; absorb the remaining liquid with sand, activated carbon or other inertia materials; Also, we can use emulsion made by inflammability dispersant to wash, let the diluted emulsion into waste water system.

Massive Leaking: Build a causeway or trenching asylum. Cover by foam to lower the harmfulness hazard of the vapors. Spray-like water-cooling and dilution steam to protect the field. With anti-explosive pump, transfer into tank car or specialized container, recycling or transport to waste disposal sites.

 

 

第七部分 操作處置與儲存

Section7 handling and storage

 

 操作注意事項：

    密閉操作，加強通風(fēng)。操作人員必須經(jīng)過專門培訓(xùn)，嚴(yán)格遵守操作規(guī)程。建議操作人員配戴自吸過濾式防毒面具，戴化學(xué)安全防護(hù)眼鏡，穿棉質(zhì)工作服。戴橡膠耐油手套。遠(yuǎn)離火種、熱源、工作場所嚴(yán)禁吸煙。使用防爆型的通風(fēng)系統(tǒng)和設(shè)備。防止大量蒸氣泄露到工作場所空氣中。避免與氧化劑接觸。灌裝時應(yīng)注意流速（不超過5M/S），且有接地裝置，防止靜電積聚。搬運時要輕裝輕卸，防止包裝及容器損壞。配置相應(yīng)品種和數(shù)量的消防器材及泄露應(yīng)急處理設(shè)備。倒空的容器可能殘留有害物。

Operation Cautions:  Enclose operation and keep air flowing. Require specialized training for operators and strict to operation instructions.  Recommend operators wearing self-contained poison-proof respirators (half mask), safety chemical goggles, protective overalls on infiltration and oil-resistant rubber protective gloves. Keep away from fire, high heat and no smoking. Use anti-explosive ventilation. Avoid vapor leak to workplace and contact with oxidant. When filling, control the speed(less than 5M/S), use the grounded equipment to avoid the accumulation of statics. Handle gently when loading and unloading in order to damage the package or containers. Equip with the appropriate variety and quantity of fire equipment and emergency equipment leakage. Emptied container may remain hazardous substance.

 

儲存注意事項：儲存于陰涼、通風(fēng)倉庫。遠(yuǎn)離火種、熱源。倉溫不宜超過30攝氏度。保持容器密封。應(yīng)與氧化劑、食用化學(xué)品分開存放。切忌混儲。采用防爆型照明、通風(fēng)設(shè)施。禁止使用易產(chǎn)生火花的機(jī)械設(shè)備和工具。儲存區(qū)應(yīng)備有泄露應(yīng)急處理設(shè)備和合適的收容材料。

Storage Cautions: store in a cool and air flowing place, keep away from fire and high heat. The temperature is below 30 Celsius degree in the storage room. Keep container sealed and separate to store with oxidant, avoid mixing storage. Use anti-explosive lighting and air flow equipment. Ban the use of the mechanic equipment and tools which are easily to cause flash fire. Emergency equipment leakage and housing materials should be available.

 

 

第八部分 接觸控制/個體防護(hù)

Section8 exposure controls/personal protection

 

 最高容許濃度： 成份中乙酯的最高容許濃度為300mg/m²；成份中甲苯最高容許濃度為100mg/m²；成份中丁酯最高容許濃度為300mg/ m²；成份中丁酮最高容許濃度為250ppm^[16，17]；成份中異丙醇最高容許濃度為1020mg/m³

Max Allowable Concentration: Ethyl ester MAX300mg/m3; toluene MAX100mg/m3; butyl ester MAX 300mg/m; butanone MAX 250ppm16,17 and isopropanol 1020mg/m3

 

監(jiān)測方法：氣相色譜法。

Monitoring Method: Gas chromatography

 

工程控制：生產(chǎn)過程密閉，加強通風(fēng)，車間，倉庫多開窗戶。裝排風(fēng)扇。組織安全淋浴和洗眼設(shè)備。

Engineering Control: Enclosed production process and increase air flowing. Install the fan and other hygiene equipment.

 

呼吸系統(tǒng)防護(hù)：空氣中濃度超標(biāo)時，建議佩戴過濾式防毒面具。緊急事態(tài)搶救或撤離時，應(yīng)該佩戴空氣呼吸器或氧氣呼吸器。

Respiratory System Protection: Wearing self-contained anti-explosive respirator(half mask) when concentration over-standard. Wearing air respirator or oxygen respirator when emergency treatment or evacuation

眼睛防護(hù)：戴化學(xué)安全防護(hù)眼鏡

Eye Protection: wearing chemical protective goggles

 

身體防護(hù)：上班時穿防毒物滲透工作服，穿勞保鞋。

Body Protection: Wearing poison-proof overalls on infiltration and safety foodwear

 

手防護(hù)：戴橡膠耐油手套

Hand Protection: Wearing oil-resistant rubber protective gloves

 

其它防護(hù)：工作現(xiàn)場禁止吸煙、進(jìn)食和飲水。工作前避免飲用酒精性飲料。工作后，沐浴更衣。進(jìn)行就業(yè)前和定期體檢。

Other Protection: No drink and no smoking on the workplace. Take a shower and put on clean clothing after work. Have a good hygiene. Regular Health check is necessary.

 

 

第九部分 理化特性

Section9 physical and chemical properties

 

 外觀與性狀：漿狀物，粘稠液體，略有刺激性氣味

Appearance and Character: pulp, thick liquid and irritating odor

PH值：5~6

主要用途：主要用作塑膠件的表面噴涂。Main Usage: Painting

溶解性：不溶于水，能與芳香烴，酯類、酮類，烷烴，醇類，丙類等多數(shù)有機(jī)溶劑混合。

Solubility: Insoluble in water and dissolve in ketones, esters, ether and so on

 

 

 

第十部分 穩(wěn)定性和反應(yīng)活性

Section10 stability and reactivity

 

 穩(wěn)定性：       穩(wěn)定

Stability: stable

禁配物：        強氧化劑

Prohibited Substance: Strong oxidant

避免接觸的條件：明火、高熱。 

Avoid Contact Condition: Open fire and high heat

聚合危害：      不能發(fā)生。

Polymer Hazard: can’t happen

分解產(chǎn)物：      一氧化碳、二氧化碳。

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